Sustainable Chemistry and Quantum Technologies
Organo-f-Synthesis
Group Agenda
57. Molecular Lanthanide Switches for Magnetism and Photoluminescence
Münzfeld L., Dahlen M., Hauser A., Mahieu N., Moutet J., Tricoire M., Köppe R., La Droitte L., Cador O., Le Guennic B., Nocton G., Moreno-Pineda E.,* Ruben M.,* Roesky P. W.*
Angew. Chem. Int. Ed., 2023, accepted, DOI: 10.1002/anie.202218107
56. Structure and Bonding Patterns in Heterometallic Organometallics with linear Ln-Pd-Ln motifs
Cemortan V., Simler T., Moutet J., Jaoul A., Clavaguéra C.,* Nocton G.*
Chem. Sci., 2023, 14, 2676-2685. DOI: 10.1039/D2SC06933D
55. Back to the future of organolanthanide chemistry
Mahieu N., Piatkowski, J., Simler T.,* Nocton G.*
Chem. Sci., 2023, 14, 443-457, DOI: 10.1039/D2SC05976B
Highlighted as 2022 ChemSci Pick of the week collection
Highlighted in the 2022 Chemical Science HOT article collection
54. Electron Shuttle in N-heteroaromatic-Ni Catalysts for Alkene Isomerization
Tricoire, M., Wang. D., Rajeshkumar, T., Maron, L.,* Danoun G.*, Nocton G.*
JACS Au, 2022, 2, 1881-1888. DOI: 10.1021/jacsau.2c00251
53. CO Reductive Oligomerization by a Divalent Thulium Complex and CO2-Induced Functionalization
Simler T.,* McCabe K. M., Maron L., Nocton G.*
Chem. Sci. 2022, 13, 7449-7461. DOI: 10.1039/D2SC01798A
Highlighted as 2022 ChemSci Pick of the week collection and
Highlighted in the 2022 Chemical Science HOT article collection
Highlighted in Chemistryworld
52. Synthesis and Structure of Tris-cyclononatetraenyl Rare Earth Complexes [Ln(C9H9)3] (Ln = Y, Gd, Tb, Dy, Ho, Er, Tm)
Stetsiuk O., La Droitte, L., Goudy, V., Le Guennic, B., Cador O., Nocton G.*
Organometallics, 2022, 41, 133-140. DOI: 10.1021/acs.organomet.1c00590
51. Size controlled hapticity switching in [Ln(C9H9)(C8H8)] sandwiches
Tricoire M., Münzfeld L., Moutet, J., Mahieu N., La Droitte L., Moreno-Pineda E., Gendron F., Hilgar, J. D., Rinehart J. D. Ruben M., Le Guennic B., Cador O. Roesky P. W. * and Nocton G.*
Chem. Eur. J., 2021, 27, 13558-13567. DOI: 10.1002/chem.202101599
Cover, DOI: 10.1002/chem.202102617
50. Intermediate valence states in lanthanides compounds
Tricoire M., Mahieu N., Simler T.*, Nocton, G.*
Chem. Eur. J., 2021, 27, 6860. DOI: 10.1002/chem.202004735
49. Influence of a Lanthanide Ion on the Ni Site of a Heterobimetallic 3d-4f Mabiq Complex
Boyce S., Moutet J., Niederegger L., Simler T., Nocton G.* Hess C.*
Inorg. Chem., 2021, 60, 403. DOI: 10.1021/acs.inorgchem.0c03058
48. Bis-cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single Molecule Magnets
Moutet J., Schleinitz J., La Droitte L., Tricoire M., Gendron F., Simler T., Clavaguéra C., Le Guennic B., Cador O., Nocton, G.*
Angew. Chem. Int. Ed., 2021, 60, 6042. DOI: 10.1002/anie.202015428
Press CNRS
47. Redox activity of a dissymmetric ligand bridging divalent ytterbium and reactive nickel fragments
Wang D., Tricoire M., Moutet J., Nocton G.*
Inorg. Chem. Front., 2021, 8, 647. DOI: 10.1039/D0QI00952K
46. Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI2
Jaoul A., Yang Y., Casaretto N., Clavaguéra C.*, Maron L.*, Nocton G.*
Chem. Commun., 2020, 56, 11875-11878. DOI: 10.1039/D0CC05164K
45. Understanding the Multiconfigurational Ground – and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies
Halbach, R., Nocton G.,* Amaro-Estrada J., Maron L., Booth C., Andersen R. A.*
Inorg. Chem., 2019, 58, 12083-12098. DOI: 10.1021/acs.inorgchem.9b01393
44. Reversible Electrons Transfers in Organolanthanide Chemistry
Jaoul A., Tricoire M., Moutet J., Cordier M., Clavaguéra C.*, Nocton G.*
Chem. Squ., 2019, 3, 1. DOI: 10.28954/2019.csq.06.001
43. Reactive Heterobimetallic Complex Combining Divalent Ytterbium and Dimethyl Nickel Fragments
Wang D., Moutet J., Tricoire M., Cordier M., Nocton G.,*
Inorganics, 2019, 7, 58. DOI: 10.3390/inorganics7050058
42. Divalent Thulium Crown-ether Complexes with Field-Induced Slow Magnetic Relaxation
Xémard M., Cordier M., Molton F., Duboc C., Le Guennic B., Maury O., Cador O., and Nocton G.*
Inorg. Chem., 2019, 58, 2872-2880. DOI: 10.1021/acs.inorgchem.8b03551
41. Lanthanidocenes: Synthesis, Structure and Bonding of Linear Sandwich Complexes of Lanthanides
Xémard M., Zimmer S., Cordier M., Goudy V., Ricard L., Clavaguéra C., Nocton G.*
J. Am. Chem. Soc., 2018, 140, 14443-14449. DOI: 10.1021/jacs.8b09081
Press CNRS
40. A Copper Iodide Nanocluster
El Moll H., Cordier M., Nocton G., Massuyeau F., Latouche C., Martineau-Corcos C., Perruchas S*
Inorg. Chem., 2018, 57, 11761-11769. DOI: 10.1021/acs.inorgchem.8b03551
39. Phenylacetylene and Carbon Dioxide Activation by an Organometallic Samarium Complex
Goudy V., Xémard M., Karleskind S., Codier M., Alvarez Lamsfus C., Maron L, Nocton G.,*
Inorganics, 2018, 6, 82. DOI: 10.3390/inorganics6030082
38. Synthesis and Reactivity of Low-Valent f-Element Iodide Complexes with Neutral Iminophosphorane Ligands
Cheisson T., Ricard L., Heinemann F. W., Meyer K.,* Auffrant A.,* Nocton G.,*
Inorg. Chem., 2018, 57, 9230-9240. DOI: 10.1021/acs.inorgchem.8b01259
37. Small molecules activation with divalent samarium triflate: a synergistic effort to cleave O2
Xémard M, Cordier M., Louyriac E., Maron L., Clavaguéra* C., Nocton, G.*
Dalton Trans., 2018, 47, 9226-9229. DOI: 10.1039/C8DT02196A
36. Cerium Tetra(tropolonate) and Cerium Tetra(acethylacetonate) are Not Diamagnetic but Temperature-Independent Paramagnets
Halbach R. L., Nocton G.,* Booth C. H., Maron L., Andersen R. A.*
Inorg. Chem., 2018, 57, 7290-7298. DOI: 10.1021/acs.inorgchem.8b00928
35. Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes
Xémard M., Goudy V., Braun A., Tricoire M., Cordier M., Ricard L., Castro L., Louyriac E., Kefalidis C. E., Clavaguera C., Maron L., Nocton G.*
Organometallics, 2017, 36, 4660-4669. DOI: 10.1021/acs.organomet.7b00630
34. Electronic structure of mono-oxidized copper and nickel phosphasalen complexes
Mustieles Marin I., Cheisson T., Chauhan R. S., Herrero C., Cordier M., Clavaguéra C.,* Nocton G.*, Auffrant A.*
Chem. Eur. J., 2017, 23, 17240-17255. DOI: 10.1002/chem.201703390
33. Tuning the stability of Pd(IV) intermediates using a redox non-innocent ligand combined with an organolanthanide fragment
Goudy V., Jaoul A., Cordier M., Clavaguéra C., Nocton G.*,
J. Am. Chem. Soc., 2017, 139, 10633-10636. DOI: 10.1021/jacs.7b05634
32. Assessment of density functionals for computing thermodynamic properties of lanthanide complexes
Jaoul A., Nocton G.*, Clavaguéra C.*
Chem. Phys. Chem., 2017, 18, 2688-2696. DOI: 10.1002/cphc.201700629
31. Effect of Cations on the Structure and Electrochemical Response of Polyoxometalate-Based Coordination Polymers
Salomon W., Paille G., Gomez-Mingot M., Mialane P., Marrot J., Nocton G., Mellot-Draznieks C., Fontecave M., Dolbecq A.*
Cryst. Growth Des., 2017, 17, 1600-1609. DOI: 10.1021/acs.cgd.6b01600
30. Divalent thulium triflate: a structural and spectroscopic study
Xémard M., Jaoul A., Cordier M., Molton F., Cador O., Le Guennic B., Duboc C., Maury O., Clavaguéra C., Nocton G.*
Angew. Chem. Int. Ed., 2017, 56, 4266-4271 (back cover). DOI: 10.1002/anie.201700576
29. Redox Initiated Reactivity of Dinuclear Niobium Imido Complexes
Kriegel B. M., Naested L. C. E., Nocton G., Lakshmi K. V., Lohrey T. D., Bergman R. G.*, Arnold J.*
Inorg. Chem., 2017, 56, 1626-1627. DOI: 10.1021/acs.inorgchem.6b02735
28. Synthesis and Characterization of 1,1’-diphosphaplumbocenes: oxidative ligand transfer with divalent thulium complexes
Jaroschik F., Momin A., Martinez A., Harakat D., Ricard L., Le Goff X.-F., Nocton, G.*
Organometallics, 2016, 35, 2032-2038. DOI: 10.1021/acs.organomet.6b00313
27. Tetramethylbiphosphinine Complexes of Cp*2Yb and Cp*2Sm: Solid-State Structure, Solution NMR Spectroscopy and Theoretical Calculations
Jaoul A., Clavaguéra C., Nocton G.*
New J. Chem., 2016, 8, 6643-6649. DOI: 10.1039/C6NJ00527F
26. η5 –η1 Iminophosphoranyl Pincer Ligands: Solid State Structures and Solution NMR 1JYb-P Coupling Constants
Cheisson T., Auffrant A., Nocton G.*
Organometallics, 2015, 34, 5470-5478. DOI: 10.1021/acs.organomet.5b00814
25. Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure and Ligand-Dependent Redox Behavior
Andrez J., Bozoklu, G., Nocton, G., Pécaut, J., Scopelliti R., Dubois, L., Mazzanti, M.*
Chem. Eur. J., 2015, 21, 15188-15200. DOI: 10.1002/chem.201502204
24. Geometry Flexibility of Copper Iodide Clusters: Variability in Luminescence Thermochromism
Benito Q., Le Goff X., Nocton G., Fargues A., Garcia A., Berhault A., Kahlal S., Saillard J. Y., Martineau C., Gacoin T., Boilot J.-P., Perruchas S.*
Inorg. Chem., 2015, 54, 4483-4494. DOI: 10.1021/acs.inorgchem.5b00321
23. Mechanochromic luminescence of Copper Iodide Clusters
Benito Q., Maurin I., Cheisson T., Nocton G., Fargues A., Garcia A., Martineau C., Gacoin T., Boilot J.-P., Perruchas S.*
Chem. A Eur. J., 2015, 21, 5892-5897. DOI: 10.1039/C9DT01161G
22. Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium
Nocton G.*, Ricard L.,
Chem. Commun., 2015, 51, 3578-3581. DOI: 10.1039/C5CC00289C
21. Electron Localization in a Mixed-valent Diniobium Benzene Complex
Gianetti T.L, Nocton G.*, Minasian S.G., Kaltsoyannis N., Kilcoyne A.L.D., Kozimor, S.A., Shuh, D.K., Tyliszczak, T., Bergman R.G.*, Arnold, J.*,
Chem. Sci., 2015, 6, 993-1003. DOI: 10.1039/C4SC02705A
20. Carbon-Hydrogen Bond Breaking and Making in the Open-Shell Singlet Molecule, Cp*2Yb(4,7-Me2phen)
Nocton G.,* Booth C. H., Maron L., Ricard A., Andersen R. A.*
Organometallics, 2014, 33, 6819-6829. DOI: 10.1021/om500843z
19. Multiple One-electron Transfers in Bipyridine Complexes of Bisphospholyl Thulium
Jacquot L., Xémard M., Clavaguéra C., Nocton G.*
Organometallics, 2014, 33, 4100-4016. DOI: 10.1021/om500607r
18. Reversible Sigma C-C Bond Formation Between Phenanthroline Ligands Activated by (C5Me5)2Yb
Nocton G.*, Lukens W. W., Booth C. H., Rozenel S. S., Medling S. A., Maron L., Andersen R. A.*
J. Am. Chem. Soc., 2014, 136, 8626-8641. DOI: 10.1021/ja502271q
17. A Phosphasalen Nickel(III) Complex
Cao T-P-A., Nocton G., Ricard L., Le Goff X. F., Auffrant A.*
Angew. Chem. Int. Ed., 2014, 53, 1368-1372. DOI: 10.1002/anie.201309222
16. N-Aromatic heterocycles adducts of bulky [1,2,4-(Me3C)C5H2]2Sm: synthesis, structure and solution analysis
Nocton G.,* Ricard L.
Dalton Trans., 2014, 43 (11), 4380-4387. DOI: 10.1039/C3DT52641K
15. The influence of the Torsion Angle in 3,3’-Dimethyl,2,2’-bipyridine on the Intermediate Valence in (C5Me5)2Yb(3,3’-Me2-bipy)
Nocton G.,* Booth C. H., Maron L., Andersen R. A.*
Organometallics, 2013, 32, 5305-5312. DOI: 10.1021/om400528d
14. CO Activation by Diphosphine-Pt(0): Carbonate and Acetone Formation. Experimental and Mechanistic Study
Nicolas E., Nocton G.*, Mézailles N.*
Eur. J. Inorg. Chem., 2013, 22-23, 4000-4007. DOI: 10.1002/ejic.201300182
13. Diniobium Inverted Sandwich Complexes with µ-n6:n6-arene Ligands: Synthesis, Kinetic of Formation, and Electronic Structure
Gianetti T.L, Nocton G., Minasian S.G., Tomson N.C., Kilcoyne A.L.D., Kozimor S.A., Shuh D.K., Tyliszczak T., Bergman R.G.*, Arnold, J.*
J. Am. Chem. Soc. 2013, 135, 3224-3236. DOI: 10.1021/ja311966h
12. Thermal Dihydrogen Elimination from Cp*2Yb(4,5-Diazafluorene)
Nocton G., Booth C. H., Maron L., Andersen R. A.*
Organometallics, 2013, 32, 1150-1158. DOI: 10.1021/om300876b
11. Synthesis and X-Ray Structure of Ruthenium bis(acetylacetonate)(N,N,N',N'-tetramethylethylenediamine)
Halbach R. L, Nocton G., Andersen R. A.*
Dalton Trans. 2012, 41, 8809-8812. DOI: 10.1039/C2DT30810J
10. High energy resolution X-ray absorption spectroscopy study of uranium in varying valence states
Vitova T.*, Kvashnina K., Nocton G., Sukharina G., Denecke M. A., Butorin S. M., Mazzanti M., Cacciuffo R., Soldatov A., Behrends T., Geckeis H.
Phys. Rev. B, 2010, 82. DOI: 10.1103/PhysRevB.82.235118
9. Cation-cation Complexes of Pentavalent Uranyl: From Disproportionation Intermediates to Stable Clusters
Mougel V., Horeglad P., Nocton G., Pécaut J., Mazzanti M.*
Chem. Eur. J., 2010, 16, 48, 14365-14377. DOI: 10.1002/chem.201001929
8. Ligand Assisted Cleavage of Uranium Oxo-Clusters
Nocton G., Pécaut J., Filinchuk Y., Mazzanti M.*
Chem. Commun. 2010, 46, 2757-2759. DOI: 10.1039/B926580E
7. Synthesis, Structure and Bonding of Stable Complexes of Pentavalent Uranyl
Nocton G., Horeglad P.,Vetere V., Pécaut J., Dubois L., Maldivi P., Edelstein N.M., Mazzanti M.*
J. Am. Chem. Soc. 2010, 132, 495-508. DOI: 10.1021/ja9037164
6. Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation-Cation Interactions
Mougel V., Horeglad P., Nocton G., Pécaut J., Mazzanti M.*
Angew. Chem. Int. Ed. 2009, 48, 8477-8480. (Inside Cover). DOI: 10.1002/anie.200903457
5. Water Stability and Luminescence of Lanthanide Complexes of Tripodal Ligands Derived from 1,4,7-triazacyclononane: pyridine carboxamide versus picolinate donors
Nocton G., Nonat A., Gateau C. and Mazzanti M.*
Helvetica Chimica Acta 2009, 92, 2257 (invited issue). DOI: 10.1002/hlca.200900150
4. Pentavalent Uranyl Stabilized by a Dianionic Bulky Tetradentate Ligand
Horeglad P., Nocton G., Filinchuk Y., Pécaut J., Mazzanti M.*
Chem. Commun. 2009, 1843-1845. DOI : 10.1039/B821398D
3. Polynuclear Cation-Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure
Nocton G., Horeglad P., Pécaut J., Mazzanti M.*
J. Am. Chem. Soc. 2008, 130, 16633-16645. DOI: 10.1039/B821398D
2. A New Nitrido-Centred Uranium Azido Cluster obtained from a Uranium Azide
Nocton G., Pécaut J., Mazzanti M.*
Angew. Chem. Int. Ed. 2008, 47, 3040-3042 (Inside cover). DOI: 10.1002/anie.200705742
1. Self-Assembly of Polyoxo Clusters and Extended Frameworks by Controlled Hydrolysis of Low Valent Uranium
Nocton G., Burdet F., Pécaut J., Mazzanti M.*
Angew. Chem. Int. Ed. 2007, 43, 7584. DOI : 10.1002/anie.200702374